JEE Advanced levelOne or more correct optionsDifficulty 3 of 3rx165
Chlorine reacts with NaOH: cold dilute, ClX2+2NaOHNaCl+NaOCl+HX2O; hot concentrated, 3ClX2+6NaOH5NaCl+NaClOX3+3HX2O. For 0.3 mol of ClX2 in each case, select the correct statement(s).
AHot reaction: 0.5 mol of electrons are transferred
BCold reaction: 0.3 mol of NaOCl is formed
CHot reaction: 0.3 mol of NaClOX3 is formed
DCold reaction: n-factor of ClX2 is 1
Answer: A, B, D
Hot: 5 electrons per 3 ClX2, so 0.3×5/3=0.5 mol e− (A true); NaClOX3=0.1 mol (C false). Cold: 1 NaOCl per ClX2, so 0.3 mol (B true); one electron is lost per ClX2, so n=1 (D true).