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Valence bond theory: hybridisation and magnetism
JEE Main level
Single correct option
Difficulty 2 of 3
cc184
The tetrahedral ion
[
FeCl
X
4
]
X
−
(
Cl
X
−
weak-field) has which hybridisation and spin-only magnetic moment?
A
d
s
p
2
,
1.73
BM
B
d
2
s
p
3
,
5.92
BM
C
s
p
3
,
1.73
BM
D
s
p
3
,
5.92
BM
Answer: D
Fe
X
3
+
is
3
d
5
and the weak-field
Cl
X
−
does not pair the electrons, so
n
=
5
. Four
Cl
X
−
use
4
s
and three
4
p
orbitals, i.e.
s
p
3
.
μ
=
5
×
7
=
5.92
BM.
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