JEE Main levelOne or more correct optionsDifficulty 2 of 3cc185
Which of the following are diamagnetic? (Use [Ni(CN)X4]X2− square planar, [NiClX4]X2− tetrahedral.)
A[Ni(CN)X4]X2−
B[Zn(NHX3)X4]X2+
C[NiClX4]X2−
D[Fe(CN)X6]X4−
Answer: A, B, D
[Ni(CN)X4]X2− is dsp2 with all electrons paired. [Zn(NHX3)X4]X2+ is 3d10. [Fe(CN)X6]X4− is low-spin d6 (t2g6). [NiClX4]X2− has two unpaired electrons, so it is paramagnetic. Correct: 1, 2 and 4.