JEE Main levelSingle correct optionDifficulty 2 of 3cc186
Which statement about the octahedral ion [Ni(NHX3)X6]X2+ is correct?
AIt is sp3d2 hybridised with a moment of 3.87 BM
BIt is sp3d2 hybridised with two unpaired electrons (2.83 BM)
CIt is d2sp3 hybridised and diamagnetic
DIt is d2sp3 hybridised with two unpaired electrons
Answer: B
NiX2+ is 3d8 (t2g6eg2), so it has two unpaired electrons and cannot free two 3d orbitals for d2sp3. It therefore uses 4s, 4p and 4d orbitals (sp3d2, outer orbital). μ=8=2.83 BM.