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JEE Main levelSingle correct optionDifficulty 2 of 3cc180

Assertion: is diamagnetic whereas is paramagnetic. Reason: The strong-field forces the electrons of to pair up and gives hybridisation, while the weak-field leaves them unpaired in an complex.

  1. ABoth Assertion and Reason are true, and the Reason is the correct explanation of the Assertion
  2. BBoth Assertion and Reason are true, but the Reason is not the correct explanation of the Assertion
  3. CAssertion is true but Reason is false
  4. DAssertion is false but Reason is true

Answer: A

Assertion is true: the cyanide complex has no unpaired electrons (, square planar) and the chloride has two (, BM). Reason is also true and it is exactly why the magnetic behaviour differs. Hence the Reason explains the Assertion.
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