JEE Main levelSingle correct optionDifficulty 2 of 3cc177
Using the spin-only formula, the hybridisation and magnetic moment of [Cr(HX2O)X6]X3+ (octahedral, Cr = 24) are respectively:
Ad2sp3, 3.87 BM
Bsp3d2, 2.83 BM
Cd2sp3, 5.92 BM
Dsp3d2, 3.87 BM
Answer: A
CrX3+ is 3d3, so the three electrons occupy three separate 3d orbitals whatever the ligand strength. Two 3d orbitals remain empty, so d2sp3 (inner orbital) is used. With n=3, μ=3×5=3.87 BM.