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JEE Main levelSingle correct optionDifficulty 2 of 3si155

Ethanamine is treated with at to give A, and A is oxidised with PCC to give B. B is

  1. Adiazoethane
  2. Bethanoic acid
  3. Cethanamide
  4. Dethanal

Answer: D

Aliphatic primary amines react with nitrous acid to give the alcohol, with evolution of : gives (A). PCC oxidises a primary alcohol only as far as the aldehyde, giving (B).
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