JEE Main levelSingle correct optionDifficulty 2 of 3si155
Ethanamine is treated with NaNOX2/HCl at 273K to give A, and A is oxidised with PCC to give B. B is
Adiazoethane
Bethanoic acid
Cethanamide
Dethanal
Answer: D
Aliphatic primary amines react with nitrous acid to give the alcohol, with evolution of NX2: CHX3CHX2NHX2 gives CHX3CHX2OH (A). PCC oxidises a primary alcohol only as far as the aldehyde, giving CHX3CHO (B).