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MolSynapse / Question bank / s-Block Elements / Important compounds: NaOH, Na2CO3, NaHCO3, CaO, CaCO3, plaster of Paris
JEE Advanced levelSingle correct optionDifficulty 3 of 3sb211

Which of the following correctly gives the order of thermal stability of the group 2 carbonates together with the reason?

  1. A; stability depends only on the molar mass of the carbonate
  2. Ball three have the same decomposition temperature because each contains
  3. C; the larger cation polarises the carbonate ion more
  4. D; the smaller cation polarises the carbonate ion more and favours formation of the oxide, which has a larger lattice enthalpy

Answer: D

Decomposition is favoured when the oxide is strongly stabilised by lattice enthalpy, which is greatest for the small and when the cation strongly polarises the carbonate ion. Hence decomposes at the lowest temperature and is the most stable.
Practice s-Block Elements More on Important compounds: NaOH, Na2CO3, NaHCO3, CaO, CaCO3, plaster of Paris

More questions on Important compounds: NaOH, Na2CO3, NaHCO3, CaO, CaCO3, plaster of Paris