JEE Advanced levelSingle correct optionDifficulty 3 of 3sb211
Which of the following correctly gives the order of thermal stability of the group 2 carbonates together with the reason?
AMgCOX3<BaCOX3<CaCOX3; stability depends only on the molar mass of the carbonate
Ball three have the same decomposition temperature because each contains COX3X2−
CBaCOX3<CaCOX3<MgCOX3; the larger cation polarises the carbonate ion more
DMgCOX3<CaCOX3<BaCOX3; the smaller cation polarises the carbonate ion more and favours formation of the oxide, which has a larger lattice enthalpy
Answer: D
Decomposition MCOX3MO+COX2 is favoured when the oxide is strongly stabilised by lattice enthalpy, which is greatest for the small MgX2+ and when the cation strongly polarises the carbonate ion. Hence MgCOX3 decomposes at the lowest temperature and BaCOX3 is the most stable.