JEE Advanced levelSingle correct optionDifficulty 3 of 3sb208
1000 L of water contains Ca(HCOX3)X2 at 0.0100 mol/L and no other hardness. By Clark's method it is softened with the least amount of pure quicklime, which is first slaked. The mass of CaO needed is (Ca 40, O 16)
A560 g
B1120 g
C1000 g
D280 g
Answer: A
CaO+HX2OCa(OH)X2 and Ca(HCOX3)X2+Ca(OH)X22CaCOX3+2HX2O are both 1 : 1. Moles of bicarbonate are 1000×0.0100=10, so 10 mol CaO is needed, which is 10×56=560 g. Using 2 mol per mole would wrongly treat each HCOX3X− separately.