JEE Advanced levelSingle correct optionDifficulty 3 of 3sb209
A mercury cathode cell for brine electrolysis carries a steady current of 9650 A for 1.00 h with a current efficiency of 80.0% for sodium deposition. All the amalgam is later converted to NaOH. Taking F = 96500 C/mol and M(NaOH) = 40 g/mol, the mass of NaOH obtained is
A14.40 kg
B5.76 kg
C11.52 kg
D18.00 kg
Answer: C
Charge used for sodium =9650×3600×0.800=2.779e+07 C, which is 288 mol of electrons. Each NaX++eX− gives one Na, and amalgam with water gives one NaOH, so 288 mol ×40 g = 11520 g = 11.52 kg.