JEE Advanced levelSingle correct optionDifficulty 3 of 3sb205
A 10.0 g mixture of NaHCOX3 and NaX2COX3 is heated strongly until the mass is constant and the solid loses 1.55 g. The percentage by mass of NaHCOX3 in the mixture is (Na 23, C 12, O 16, H 1)
A36.9%
B15.5%
C42.0%
D58.0%
Answer: C
Only NaHCOX3 decomposes: 2NaHCOX3NaX2COX3+COX2+HX2O, with 62 g lost per 168 g. Mass of NaHCOX3=1.55×168/62=4.20 g, which is 42.0% of 10.0 g. The value 15.5% is simply the mass loss as a percentage.