JEE Advanced levelSingle correct optionDifficulty 3 of 3sb203
Match the compound in List I with the statement in List II. List I: (P) CaCOX3; (Q) Ca(OH)X2; (R) NaHCOX3; (S) CaSOX4⋅2HX2O. List II: (1) loses mass near 400 K, releasing both COX2 and steam; (2) decomposes only near 1100 K to a basic oxide and COX2; (3) its clear aqueous solution turns milky on passing a little COX2; (4) on heating to 393 K gives a solid that sets to a hard mass with water.
AP-2, Q-3, R-1, S-4
BP-2, Q-1, R-3, S-4
CP-3, Q-2, R-1, S-4
DP-2, Q-3, R-4, S-1
Answer: A
CaCOX3CaO+COX2 needs about 1100 K (P-2). Lime water, a solution of Ca(OH)X2, turns milky with COX2 (Q-3). NaHCOX3 gives COX2 and HX2O near 400 K (R-1). Gypsum gives plaster of Paris at 393 K, which sets with water (S-4).