JEE Advanced levelSingle correct optionDifficulty 3 of 3sb204
530 g of NaX2COX3 is fully converted to NaOH by boiling with excess slaked lime, and all the NaOH is then treated with excess chlorine in hot concentrated solution. The mass of NaClOX3 formed is (Na 23, C 12, O 16, Cl 35.5; assume complete reactions)
A177.5 g
B355.0 g
C106.5 g
D372.5 g
Answer: A
NaX2COX3+Ca(OH)X22NaOH+CaCOX3: 530/106=5.00 mol carbonate gives 10.00 mol NaOH. Hot concentrated alkali: 3ClX2+6NaOH5NaCl+NaClOX3+3HX2O, so 10.00/6 = 1.667 mol NaClOX3 (106.5 g/mol), mass 177.5 g. The value 372.5 g would correspond to NaOCl from the cold dilute reaction.