JEE Advanced levelSingle correct optionDifficulty 3 of 3sb074
Beryllium carbide and aluminium carbide both react with water to give the same hydrocarbon gas G and the corresponding amphoteric hydroxide. If 0.10 mol of BeX2C and 0.10 mol of AlX4CX3 are hydrolysed separately and the gases are pooled, the volume of G at STP (22.4 L per mol) is
A13.44 L
B4.48 L
C6.72 L
D8.96 L
Answer: D
BeX2C+4HX2O2Be(OH)X2+CHX4 gives 1 mol G per mol, and AlX4CX3+12HX2O4Al(OH)X3+3CHX4 gives 3 mol G per mol. Total G =0.10+0.30=0.40 mol, so volume =0.40×22.4=8.96 L.