JEE Advanced levelSingle correct optionDifficulty 3 of 3sb073
A light silvery metal M floats on water. It burns in air to give a white mixture of its oxide and a nitride Q. Q reacts with water to give an alkaline gas. The nitrate of M on strong heating gives a brown gas and a gas that rekindles a glowing splint. The solid residue obtained on heating the nitrate of M is
ALiNOX2
BLiOX2
CLiX2O
DLiX2OX2
Answer: C
A metal that floats on water and forms a nitride on burning is Li (Mg and Ca are denser than water). LiX3N+3HX2O3LiOH+NHX3 gives the alkaline gas. Unlike the other alkali nitrates, LiNO3 decomposes as 4LiNOX32LiX2O+4NOX2+OX2, so the residue is LiX2O.