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JEE Main levelOne or more correct optionsDifficulty 2 of 3sb072

Which of the following statements about beryllium compounds are correct?

  1. AAnhydrous beryllium chloride dissolves in diethyl ether
  2. BBeryllium chloride has a higher melting point than magnesium chloride because Be2+ is smaller
  3. CBe(II) in water exists as
  4. DAqueous solutions of beryllium salts are acidic because of hydrolysis of

Answer: A, D

The tiny Be2+ polarises coordinated water so is acidic, and covalent BeCl2 dissolves in ether. Be has a maximum coordination number of 4 (no ), and covalent BeCl2 (about 688 K) melts lower than ionic MgCl2 (about 987 K).
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