JEE Advanced levelSingle correct optionDifficulty 3 of 3sb076
Equal numbers of moles of anhydrous LiNOX3 and NaNOX3 are heated strongly until decomposition is complete, giving the oxide and nitrogen dioxide with oxygen for lithium, but the nitrite and oxygen for sodium. The ratio (moles of gas from LiNO3) : (moles of gas from NaNO3) is
A5.0
B2.5
C1.25
D2.0
Answer: B
Per mole, 4LiNOX32LiX2O+4NOX2+OX2 gives 1+0.25=1.25 mol gas, and 2NaNOX32NaNOX2+OX2 gives 0.5 mol gas. The ratio is 1.25/0.50=2.5.