JEE Advanced levelSingle correct optionDifficulty 3 of 3rx079
In alkaline medium oxalate is oxidised to carbonate by permanganate, which is reduced to MnOX2. The balanced equation (smallest whole numbers) contains OHX− with coefficient
A4 (product side)
B2 (reactant side)
C4 (reactant side)
D6 (reactant side)
Answer: C
Mn gains 3 electrons and each oxalate loses 2, so MnOX4X− : CX2OX4X2− = 2 : 3. Charge on the left is -2 -6 = -8 while the 6 carbonate on the right carry -12, so 4 OHX− must be added on the left. Balanced: 2MnOX4X−+3CX2OX4X2−+4OHX−2MnOX2+6COX3X2−+2HX2O.