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JEE Advanced levelSingle correct optionDifficulty 3 of 3rx079

In alkaline medium oxalate is oxidised to carbonate by permanganate, which is reduced to . The balanced equation (smallest whole numbers) contains with coefficient

  1. A4 (product side)
  2. B2 (reactant side)
  3. C4 (reactant side)
  4. D6 (reactant side)

Answer: C

Mn gains 3 electrons and each oxalate loses 2, so : = 2 : 3. Charge on the left is -2 -6 = -8 while the 6 carbonate on the right carry -12, so 4 must be added on the left. Balanced: .
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