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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3rx078

Use average oxidation numbers of sulphur. Select ALL correct statements about thiosulphate .

  1. AThe average oxidation number of S in is +2
  2. BThe n-factor of in its oxidation to by is 1
  3. CThe n-factor of in its oxidation to by is 8
  4. DThe average oxidation number of S in is +3

Answer: A, B, C

In : 2x - 6 = -2, so x = +2. In : 4x - 12 = -2, so x = +2.5 (not +3), making statement 4 false. For to , 2 thiosulphate lose 2 electrons in total (2 x 2 -> 4 x 2.5), so n-factor = 1. To sulphate, each S goes +2 to +6, so n-factor = 2 x 4 = 8.
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