JEE Advanced levelSingle correct optionDifficulty 3 of 3rx077
In basic medium manganese dioxide is oxidised by chlorate: MnOX2+ClOX3X−+OHX−MnOX4X2−+ClX−+HX2O. The sum of all coefficients (smallest whole numbers, reactants and products) is
A17
B20
C11
D14
Answer: A
Mn goes +4 to +6 (loses 2) and Cl goes +5 to -1 (gains 6), so MnOX2 : ClOX3X− = 3 : 1. Charge balance (right side -7) needs 6 OHX− on the left, and then 3 HX2O balance O and H: 3MnOX2+ClOX3X−+6OHX−3MnOX4X2−+ClX−+3HX2O. The coefficients add up to 17.