JEE Main levelNumerical answerDifficulty 2 of 3rg105
A gas has Z=0.9880 at a molar volume of 5.00Lmol−1. Neglecting the third and higher virial terms, its second virial coefficient B in mLmol−1 (nearest integer) is
Numerical answer type, answer in mL/mol, tolerance 1.
Answer: -60 mL/mol
Z=1+B/Vm, so B=(Z−1)Vm=(0.9880−1)(5.00)=−0.0600Lmol−1=−60mLmol−1.