JEE Advanced levelSingle correct optionDifficulty 3 of 3ph149
Xe and FX2 react at 573 K and 60-70 bar to give compound X. X is partially hydrolysed with one mole of water to Y, and Y with a further mole of water gives Z (a see-saw molecule). Counting each Xe=O as one σ bond, the total number of Xe-centred σ bonds in Y and Z together is
A8
B9
C10
D11
Answer: B
X is XeFX6; Y is XeOFX4 (5 sigma bonds: 4 Xe-F and 1 Xe-O); Z is XeOX2FX2 (4 sigma bonds: 2 Xe-F and 2 Xe-O, see-saw). Total = 5+4=9.