JEE Advanced levelSingle correct optionDifficulty 3 of 3ph147
In alkaline solution HXeOX4X− disproportionates: 2HXeOX4X−+2OHX−XeOX6X4−+Xe+OX2+2HX2O. If 0.60mol of HXeOX4X− reacts completely, the mass of xenon gas liberated is (Xe = 131)
A39.3 g
B78.6 g
C19.65 g
D26.2 g
Answer: A
The balanced equation gives 1 mol of Xe per 2 mol of HXeOX4X− (Xe(VI) goes to Xe(VIII) and Xe(0)). Moles of Xe = 0.60/2=0.30. Mass = 0.30×131=39.3g.