JEE Advanced levelSingle correct optionDifficulty 3 of 3pb143
A salt solution gives a white gelatinous precipitate with aqueous ammonia that does not dissolve in excess; the precipitate dissolves in excess NaOH, and adding NHX4Cl to that alkaline solution reprecipitates the white solid. The cation is
AZnX2+
BMgX2+
CCuX2+
DAlX3+
Answer: D
Al(OH)X3 is amphoteric, soluble in excess NaOH as [Al(OH)X4]X−, and NHX4X+ lowers the pH so Al(OH)X3 reappears. Zn(OH)X2 dissolves in excess ammonia, Mg(OH)X2 is insoluble in excess NaOH, and Cu(II) gives a blue precipitate.