JEE Advanced levelSingle correct optionDifficulty 3 of 3pb141
In Baeyer's process for purifying bauxite, which description is correct?
AAlX2OX3 dissolves in conc. NaOH as [Al(OH)X4]X− leaving FeX2OX3 as red mud; COX2 then precipitates Al(OH)X3, which is ignited to AlX2OX3
BFeX2OX3 dissolves in NaOH as ferrate and AlX2OX3 remains as the residue
CAlX2OX3 dissolves as AlX3+ and excess NaOH precipitates Al(OH)X3
DAlX2OX3 is reduced by NaOH to Al metal, which is then oxidised by COX2
Answer: A
Amphoteric AlX2OX3 dissolves as aluminate while basic FeX2OX3 stays undissolved. Acidifying with COX2 gives 2Na[Al(OH)X4]+COX22Al(OH)X3+NaX2COX3+HX2O and ignition at high temperature gives pure AlX2OX3.