JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ig159
10mL of a gaseous hydrocarbon is mixed with 70mL of OX2 and exploded. After cooling to room temperature the volume is 50mL; after KOH it is 20mL; after alkaline pyrogallol it is 0mL. Which statements are correct?
AThe hydrocarbon contains 3 carbon atoms per molecule
BThe hydrocarbon contains 8 hydrogen atoms per molecule
CThe volume of OX2 consumed is 50mL
DThe hydrocarbon is propane
Answer: A, B, C, D
COX2=50−20=30, so x=3 (A). Residual OX2=20 (all absorbed by pyrogallol), so OX2 used =50mL (C). 10(3+y/4)=50 gives y=8 (B). CX3HX8 is propane (D). All correct.