JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ig158
A porous partition separates two compartments. Compartment 1 contains HX2 at 1atm and compartment 2 contains OX2 at 1atm, both at the same temperature. Which statements are correct for the initial stage of diffusion?
AHX2 crosses into compartment 2 four times faster than OX2 crosses into compartment 1
BThe pressure in compartment 2 initially rises
CThe pressure in compartment 1 initially falls
DThe number of molecules crossing per second is the same in both directions
Answer: A, B, C
Rates ∝p/M with equal p: 32/2=4 (A). More molecules enter compartment 2 than leave it, so its pressure rises (B) and that of compartment 1 falls (C). The flows are unequal, so (D) is wrong.