JEE Advanced levelSingle correct optionDifficulty 3 of 3ig147
50mL of a mixture of CO, COX2 and NX2 was treated with KOH, reducing the volume to 40mL. The remaining gas was mixed with 20mL of OX2 and exploded, and after cooling and KOH treatment the volume was 15mL. The volume of CO in the original mixture was
A30mL
B20mL
C10mL
D15mL
Answer: A
COX2=50−40=10mL. Let CO=a and NX2=40−a. 2CO+OX22COX2 consumes a/2 of OX2 and the COX2 formed is removed by KOH. Residual =NX2+leftover OX2=(40−a)+(20−a/2)=15, so 1.5a=45 and a=30mL.