JEE Advanced levelSingle correct optionDifficulty 3 of 3ig204
30mL of a mixture of CHX4 and CX2HX6 was burnt in excess OX2. After cooling, the COX2 formed was absorbed by KOH and the contraction on absorption was 40mL. The mole fraction of CX2HX6 in the mixture was
A31
B32
C21
D41
Answer: A
Let CHX4=a, CX2HX6=30−a. COX2=a+2(30−a)=60−a=40, so a=20 and CX2HX6=10mL. Mole fraction =10/30=1/3.