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JEE Main levelSingle correct optionDifficulty 2 of 3hc241

The carboxylic acid shown is converted to its sodium salt and heated with soda lime. Which structure is the hydrocarbon formed?

  1. AStructure A
  2. BStructure B
  3. CStructure C
  4. DStructure D

Answer: A

The compound shown is 3-methylbutanoic acid. Decarboxylation with soda lime removes the carboxyl carbon as carbonate and puts H in its place, so the alkane has one carbon fewer: the four-carbon branched 2-methylpropane. Butane has the wrong skeleton and 2-methylbutane has the carbon count of the acid.
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