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JEE Advanced levelSingle correct optionDifficulty 3 of 3df153

Assertion (A): Replacing water by ethane-1,2-diamine turns the green into violet , and both complexes have two unpaired electrons. Reason (R): en is a stronger-field ligand than water, which increases the splitting and shifts absorption to a shorter wavelength, but a ion in an octahedral field always has two unpaired electrons.

  1. ABoth A and R are true and R is the correct explanation of A
  2. BBoth A and R are true but R is not the correct explanation of A
  3. CA is true but R is false
  4. DA is false but R is true

Answer: A

A: en raises and shifts the absorption bands to shorter wavelength, changing the colour, so the first part is true. Both complexes are octahedral (), so both have 2 unpaired electrons whatever the ligand. R states exactly this and explains both observations in A.
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