JEE Advanced levelSingle correct optionDifficulty 3 of 3df154
It is observed empirically that LnX3+ ions with 4fn and 4f(14−n) configurations have similar colours. Which pair of ions is expected to have similar colours?
ACeX3+ (Z=58) and EuX3+ (Z=63)
BSmX3+ (Z=62) and GdX3+ (Z=64)
CPrX3+ (Z=59) and TmX3+ (Z=69)
DNdX3+ (Z=60) and DyX3+ (Z=66)
Answer: C
For LnX3+ the number of 4f electrons is Z−54. Pr gives 2 and Tm gives 12, which add up to 14. The other pairs are 3 and 9 (12), 1 and 6 (7), and 5 and 7 (12). Only Pr and Tm complement each other.