NEET levelSingle correct optionDifficulty 1 of 3cc169
FX− is a weak-field ligand, so [CoFX6]X3− is high spin. The number of unpaired electrons and the hybridisation of Co in this ion are:
A0, d2sp3
B4, sp3d2
C2, sp3d2
D4, d2sp3
Answer: B
CoX3+ is 3d6. With a weak-field ligand the electrons are not paired: the configuration is t2g4eg2 with four unpaired electrons. The six FX− use 4s, 4p and two 4d orbitals, giving sp3d2 (outer orbital).