JEE Advanced levelOne or more correct optionsDifficulty 3 of 3td220
A reaction has ΔH∘=+30.0kJmol−1 and ΔS∘=+100Jmol−1K−1, both independent of temperature (R=8.314Jmol−1K−1). Select all correct statements.
AK=1 at 300K
BΔG∘=+5.0kJmol−1 at 350K
CK≈0.090 at 250K
DK≈5.6 at 350K
Answer: A, C, D
K=1 when ΔG∘=0, i.e. T=30000/100=300K. At 350K, ΔG∘=30000−35000=−5000J, not +5.0kJ, and K=exp(5000/(8.314×350))=5.57. At 250K, ΔG∘=+5000J and K=exp(−5000/(8.314×250))=0.0902.