JEE Advanced levelSingle correct optionDifficulty 3 of 3so158
100mL of 0.30M glucose is mixed with 200mL of 0.15MNaCl (complete dissociation, volumes additive) at 300K. With R=0.0821Latmmol−1K−1, the osmotic pressure of the mixture is
A4.93atm
B7.39atm
C5.54atm
D14.78atm
Answer: B
Particles: glucose 0.100×0.30=0.030 mol and NaCl0.200×0.15×2=0.060 mol, total 0.090 mol in 0.300 L, i.e. 0.300 M. π=0.300×0.0821×300=7.39 atm. Ignoring dissociation gives 4.93 atm.