JEE Advanced levelNumerical answerDifficulty 3 of 3so160
A 0.040M solution of KX3[Fe(CN)X6] is 70% dissociated (KX3[Fe(CN)X6]3KX++[Fe(CN)X6]X3−; use i=1+(n−1)α). At the same temperature, what mass of glucose (molar mass 180gmol−1) per litre of solution is isotonic with it? Give the answer in g to two decimal places.
Numerical answer type, answer in g, tolerance 0.01.
Answer: 22.32 g
Each formula unit gives n=4 ions, so i=1+3×0.70=3.10. Effective concentration =0.040×3.10=0.124 M. Isotonic glucose is 0.124 M, so mass per litre =0.124×180=22.32 g.