JEE Main levelNumerical answerDifficulty 2 of 3rx021
In the thiosulfate ion SX2OX3X2− (structure S−SOX3X2−), the two sulfur atoms have different individual oxidation numbers. Use the common textbook convention in which the terminal (sulfane) sulfur is treated like a sulfide sulfur. Find the numerical difference between the oxidation number of the central (sulfonate-type) S and that of the terminal S.
Numerical answer type, tolerance 0.01.
Answer: 8
The terminal sulfane S is −2 (like sulfide). For the ion, −2+x+3(−2)=−2 gives the sulfonate S as x=+6. The difference is 6−(−2)=8.