JEE Main levelSingle correct optionDifficulty 2 of 3rx018
Using bond-counting by electronegativity (O>C>H, C-C bonds count zero), the oxidation numbers of the methyl carbon and the carboxyl carbon in acetic acid, CHX3COOH, are respectively
A−3 and +3
B0 and 0
C−4 and +4
D−3 and +4
Answer: A
Methyl C has three C-H bonds: 3(−1)=−3. Carboxyl C has C=O (+2) and C-OH (+1): +3. The sum is 0, matching the average of 0 for CX2HX4OX2.