JEE Advanced levelOne or more correct optionsDifficulty 3 of 3rg198
The Boyle temperatures of three gases are: P, 23K; Q, 110K; R, 715K. Which statements are correct regarding their behaviour at 200K?
AP and Q have Z greater than 1 at all pressures
BR shows a minimum in its Z versus P curve
CP warms on Joule-Thomson expansion
DQ warms on Joule-Thomson expansion
Answer: A, B, C
200K is above TB of P and Q, so both have Z above 1 everywhere (A true), and below TB of R, so R shows a dip (B true). Ti=2TB: P has Ti=46K, so it warms (C true); Q has Ti=220K, above 200K, so Q cools (D false).