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Boyle temperature and inversion temperature
JEE Main level
Numerical answer
Difficulty 2 of 3
rg026
For nitrogen
a
=
1.39
L
2
atm
mo
l
−
2
and
b
=
0.0391
L
mo
l
−
1
. Its Boyle temperature in K (nearest integer), using
R
=
0.0821
L
atm
K
−
1
mo
l
−
1
, is
Numerical answer type, answer in K, tolerance 2.
Answer: 433 K
T
B
=
R
b
a
=
0.0821
×
0.0391
1.39
=
0.003210
1.39
=
433.0
K
, i.e.
433
K
. Nitrogen at room temperature is below
T
B
, so
Z
dips below 1 at moderate pressures.
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