JEE Main levelNumerical answerDifficulty 2 of 3rg008
At 20atm and 400K the compressibility factor of COX2 (molar mass 44gmol−1) is 0.92. Using R=0.0821LatmK−1mol−1, the density of the gas in gL−1 (two decimals) is
Numerical answer type, answer in g/L, tolerance 0.02.
Answer: 29.13 g/L
From Z=PM/(ρRT), ρ=ZRTPM=0.92×0.0821×40020×44=30.213880=29.127gL−1, i.e. 29.13gL−1. The real gas is denser than the ideal value 32.84880=26.80gL−1.