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Deviation from ideal behaviour and compressibility factor
JEE Main level
Single correct option
Difficulty 2 of 3
rg007
A gas of molar mass
M
has density
ρ
at pressure
P
and temperature
T
. Its compressibility factor is given by
A
Z
=
PM
ρRT
B
Z
=
ρRT
PM
C
Z
=
MRT
Pρ
D
Z
=
Pρ
MRT
Answer: B
For
n
moles,
Z
=
P
V
/
n
RT
. With
n
=
m
/
M
and
ρ
=
m
/
V
,
V
/
n
=
M
/
ρ
, so
Z
=
ρRT
PM
. A real gas denser than the ideal prediction has
Z
less than 1.
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