JEE Advanced levelNumerical answerDifficulty 3 of 3rg010
A cylinder of volume 2.0L contains nitrogen at 100atm and 300K, where Z=1.25. The mass of nitrogen in the cylinder, in grams (one decimal), is (molar mass of NX2=28gmol−1, R=0.0821LatmK−1mol−1)
Numerical answer type, answer in g, tolerance 0.2.
Answer: 181.9 g
n=ZRTPV=1.25×0.0821×300100×2.0=30.7875200=6.4961mol. Mass =6.4961×28=181.89g, i.e. 181.9g. Treating the gas as ideal would overestimate the mass by 25 percent.