JEE Advanced levelSingle correct optionDifficulty 3 of 3qa181
A sodium salt X gives a colourless pungent gas with dilute HX2SOX4. The gas turns lime water milky, the milkiness disappears on passing excess gas, and the gas decolourises acidified KMnOX4. X and the species responsible for the clearing are
ANaX2COX3 and Ca(HCOX3)X2
BNaX2SOX3 and Ca(HSOX3)X2
CNaX2S and Ca(HS)X2
DNaX2SOX3 and CaSOX4
Answer: B
Decolourising acidified KMnOX4 and the pungent smell rule out COX2 and point to SOX2. SOX2+Ca(OH)X2CaSOX3+HX2O gives the milkiness and CaSOX3+SOX2+HX2OCa(HSOX3)X2 (soluble) clears it. The salt is sodium sulphite; COX2 would not decolourise permanganate and HX2S is not given by sulphite.