JEE Advanced levelOne or more correct optionsDifficulty 3 of 3qa105
Which statements about the thiosulphate ion are correct? One or more options may be correct.
AWith dilute HCl it gives a turbidity of sulphur and evolves SOX2.
BThe average oxidation state of sulphur in SX2OX3X2− is +2.
CIt reduces iodine to iodide, forming tetrathionate: 2SX2OX3X2−+IX2SX4OX6X2−+2IX−.
DWith dilute HCl it gives a perfectly clear solution and no gas.
Answer: A, B, C
SX2OX3X2−+2HX+S+SOX2+HX2O gives both turbidity and SOX2. The average S oxidation state is 2x+3(−2)=−2, so x=+2. Iodine oxidises it to SX4OX6X2− (charge and atoms balance). The clear-solution statement is false. Correct: first three.