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JEE Main levelSingle correct optionDifficulty 2 of 3qa047

Match the anion in List I with the observation on warming its solid with conc. in List II. List I: (P) (Q) (R) (S) List II: (1) colourless pungent gas giving dense white fumes with a rod dipped in (2) reddish-brown vapours (3) violet vapours (4) colourless gases, one of which burns with a blue flame

  1. AP-1, Q-2, R-3, S-4
  2. BP-2, Q-1, R-3, S-4
  3. CP-1, Q-3, R-2, S-4
  4. DP-1, Q-2, R-4, S-3

Answer: A

Chloride gives HCl, which forms white fumes with ammonia. Bromide is oxidised to reddish-brown and iodide to violet . Oxalate gives CO (blue flame) and . The match is P-1, Q-2, R-3, S-4.
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