JEE Main levelSingle correct optionDifficulty 2 of 3qa047
Match the anion in List I with the observation on warming its solid with conc. HX2SOX4 in List II.
List I: (P) ClX− (Q) BrX− (R) IX− (S) CX2OX4X2−
List II: (1) colourless pungent gas giving dense white fumes with a rod dipped in NHX3 (2) reddish-brown vapours (3) violet vapours (4) colourless gases, one of which burns with a blue flame
AP-1, Q-2, R-3, S-4
BP-2, Q-1, R-3, S-4
CP-1, Q-3, R-2, S-4
DP-1, Q-2, R-4, S-3
Answer: A
Chloride gives HCl, which forms white NHX4Cl fumes with ammonia. Bromide is oxidised to reddish-brown BrX2 and iodide to violet IX2. Oxalate gives CO (blue flame) and COX2. The match is P-1, Q-2, R-3, S-4.