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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3qa050

Which of the following statements about the silver halides are correct?

  1. AAgCl dissolves in dilute ammonia as .
  2. BAgBr dissolves readily in dilute ammonia to give a clear solution.
  3. CAgI does not dissolve in conc. ammonia.
  4. DAgCl, AgBr and AgI all dissolve in excess sodium thiosulphate solution through .

Answer: A, C, D

AgCl is soluble in dilute ammonia; AgBr only in conc. ammonia, so statement 2 is false. AgI has a very small and is insoluble in ammonia. All three dissolve in thiosulphate by forming , which is a much stronger complex.
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