JEE Main levelSingle correct optionDifficulty 2 of 3qa044
A sodium salt is warmed with conc. HX2SOX4 and the gas mixture (HX2CX2OX4CO+COX2+HX2O for the acid formed) is passed through conc. NaOH solution. The gas that leaves the NaOH, and the moles of it from 1 mol oxalate, are respectively
AHX2 ; 1
BCOX2 ; 1
CCO ; 1
DCO ; 2
Answer: C
Conc. HX2SOX4 dehydrates oxalic acid to equal moles of CO and COX2. NaOH absorbs acidic COX2, leaving CO that burns with a blue flame. 1 mol oxalate gives 1 mol CO.