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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3qa048

Which of the following statements about the chromyl chloride test are correct?

  1. AChromium has the oxidation state +6 in both and .
  2. BThe test is not given by because it is covalent and does not release free chloride ions.
  3. C has a tetrahedral molecular geometry.
  4. DThe test works equally well if the solid dichromate is replaced by dilute only.

Answer: A, B, C

Both Cr atoms are +6 in and in , so 1 is true. Covalent gives no free , so 2 is true. The molecule is tetrahedral (Cr with two oxo and two chloro ligands), so 3 is true. Statement 4 is false: solid dichromate and concentrated acid are both needed.
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