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JEE Advanced levelSingle correct optionDifficulty 3 of 3pl155

Which statement distinguishes step-growth (condensation) polymerisation of adipic acid and hexamethylenediamine from chain-growth addition polymerisation?

  1. AThe growing chain carries a radical that adds to the next monomer
  2. BA high molar mass is reached only when the functional groups have reacted to a very high conversion, because oligomers couple with each other throughout the reaction
  3. CHigh-molar-mass chains are formed from the start while most of the monomer is still unreacted
  4. DOnly monomer molecules add to the growing chain end, one at a time

Answer: B

In step growth any two molecules with reactive ends (monomer, dimer, oligomer) can couple, so monomer is used up early but molar mass climbs only at conversions close to 100 percent. The other three statements describe chain-growth addition.
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